Identifying critical nodes in networks is a classical decision-making task, and many methods struggle to strike a balance between adaptability and utility. Therefore, we propose an approach that empowers Evolutionary Algorithm (EA) with Large Language Models (LLMs), to generate a function called "score\_nodes" which can further be used to identify crucial nodes based on their assigned scores. Our model consists of three main components: Manual Initialization, Population Management, and LLMs-based Evolution. It evolves from initial populations with a set of designed node scoring functions created manually. LLMs leverage their strong contextual understanding and rich programming skills to perform crossover and mutation operations on the individuals, generating excellent new functions. These functions are then categorized, ranked, and eliminated to ensure the stable development of the populations while preserving diversity. Extensive experiments demonstrate the excellent performance of our method, showcasing its strong generalization ability compared to other state-of-the-art algorithms. It can consistently and orderly generate diverse and efficient node scoring functions. All source codes and models that can reproduce all results in this work are publicly available at this link: \url{https://anonymous.4open.science/r/LLM4CN-6520}