LLM-based agents are increasingly applied to the "last mile" of Electronic Design Automation (EDA): repairing residual sign-off Design Rule Check (DRC) violations and converging Power-Performance-Area (PPA) targets after tool runs. Existing EDA-LLM benchmarks, however, omit DRC fixing entirely and rely on flat hierarchies tied to a single toolchain. We introduce PostEDA-Bench, a hierarchical benchmark with 145 tasks across DRC-Essential, DRC-Reasoning, PPA-Mono, and PPA-Multi, supported by EDA toolchains with machine-checkable evaluation. Across eight commercial and open-source LLMs under multiple agent scaffolds, we find that agents handle synthetic DRC-Essential and single-objective PPA-Mono reasonably well but degrade sharply on the more practical DRC-Reasoning, where the best success rate is 36.66%, and PPA-Multi, where the best success rate is 20.00%; vision augmentation consistently enhances DRC-Bench; and trade-off reasoning, rather than knob knowledge, is the dominant PPA-Multi bottleneck.