Doppler-resilient complementary sequence (DRCS) sets play a vital role in modern communication and sensing systems, particularly in high-mobility environments. This work makes two primary contributions. First, we refine the definition of quasi-Florentine rectangles to a more general form,termed generalized quasi-Florentine rectangles, and propose a systematic method for their construction. Second, we propose several sets of aperiodic DRCS based on generalized quasi Florentine rectangles and Butson-type Hadamard matrices. The proposed aperiodic DRCS sets are shown to be asymptotically optimal with respect to the lower bound of aperiodic DRCS sets.