Bluetooth Low Energy (BLE) CTE transmissions provide in-phase and quadrature (IQ) samples whose empirical statistics are strongly governed by the propagation regime. in particular, the distributions differ markedly between line-of-sight (LOS) and non-line-of-sight (NLOS) conditions. In NLOS, multipath-induced distortions typically degrade Angle-of-Arrivial (AoA) estimation accuracy. Existing BLE direction finding datasets rarely provide tightly controlled, IQ-level paired LOS and NLOS measurements with rigorous statistical validation, and commonly used flat-fading models can be inadequate for cluttered indoor environments exhibiting heavy-tailed power distributions. To address these limitations, we conduct a paired-geometry BLE AoA measurement campaign using an off-the-shelf module, collecting 132000 labeled CTE packets under matched anchor-tag conditions. A robust preprocessing stage removes anomalous CTEs using combined univariate and multivariate criteria. Feature-wise hypothesis tests on IQ-derived power features confirm strong LOS and NLOS separability. All mean differences are statistically significant; additionally, 92 percent of feature-wise variance differences are significant. We further compute L-moment ratios (LMRs) and analyze them in the L-moment Ratio Diagram (LMRD), showing that NLOS subsets exhibit markedly heavier tails and stronger asymmetry than LOS. Kappa-family distributions fitted from LMRs provide substantially improved dual scored L--moment goodness-of-fit (GoF), Specifically, for NLOS, which is the smallest discrepancy in the LMRD and a near-zero standardized L-kurtosis deviation. As a practice, we apply a self-supervised clustering to L-moment statistics, achieving a more separable representation, compared to product moments.