Mobile communication networks were designed to mainly support ubiquitous wireless communications, yet they are also expected to achieve radio sensing capabilities in the near future. However, most prior studies on radio sensing usually rely on far-field assumption with uniform plane wave (UPW) models. With the ever-increasing antenna size, together with the growing demands to sense nearby targets, the conventional far-field UPW assumption may become invalid. Therefore, this paper studies near-field radio sensing with extremely large-scale (XL) antenna arrays, where the more general uniform spheric wave (USW) sensing model is considered. Closed-form expressions of the Cramér-Rao Bounds (CRBs) for both angle and range estimations are derived for near-field XL-MIMO radar mode and XL-phased array radar mode, respectively. Our results reveal that different from the conventional UPW model where the CRB for angle decreases unboundedly as the number of antennas increases, for XL-MIMO radar-based near-field sensing, the CRB decreases with diminishing return and approaches to a certain limit as the number of antennas increases. Besides, different from the far-field model where the CRB for range is infinity since it has no range estimation capability, that for the near-field case is finite. Furthermore, it is revealed that the commonly used spherical wave model based on second-order Taylor approximation is insufficient for near-field CRB analysis. Extensive simulation results are provided to validate our derived CRBs.