We investigate deterministic identification over arbitrary memoryless channels under the constraint that the error probabilities of first and second kind are exponentially small in the block length $\mathbf{n}$, controlled by reliability exponents $\mathbf{E_1,E_2 \geq 0}$. In contrast to the regime of slowly vanishing errors, where the identifiable message length scales linearithmically as $\mathbf{Θ(n\log n)}$, here we find that for positive exponents linear scaling is restored, now with a rate that is a function of the reliability exponents. We give upper and lower bounds on the ensuing rate-reliability function in terms of (the logarithm of) the packing and covering numbers of the channel output set, which for small error exponents $\mathbf{E_1,E_2>0}$ can be expanded in leading order as the product of the Minkowski dimension of a certain parametrisation the channel output set and $\mathbf{\log\min\{E_1,E_2\}}$. These allow us to recover the previously observed slightly superlinear identification rates, and offer a different perspective for understanding them in more traditional information theory terms. We also show that even if only one of the two errors is required to be exponentially small, the linearithmic scaling is lost. We further illustrate our results with a discussion of the case of dimension zero, and extend them to classical-quantum channels and quantum channels with tensor product input restriction.