Large propagation path loss and limited scattering of millimeter wave (mmwave) channels create new challenges for physical layer signal processing. Hence, in this article, we propose a photonic hybrid precoding model for mmwave radio-over-fiber systems that overcomes hardware constraints on radio frequency precoding. With help of silicon photonic integrated circuits (Si-PICs), the photonic precoding strategy combats the large losses of mmwave and mitigates inter-user interference. Simulation results show that the proposed model can offer significant coding gains over conventional precoding systems.