Optical wireless communication (OWC) is envisioned as a key enabler for immersive indoor data transmission in future wireless communication networks. However, multi-user interference management arises as a challenge in dense indoor OWC systems composed of multiple optical access points (APs) serving multiple users. In this paper, we propose a novel dual-function OWC system for communication and localization. Non-orthogonal multiple access (NOMA) with random linear network coding (RLNC) is designed for data transmission, where NOMA allows the serving of multiple users simultaneously through controlling the power domain, and RLNC helps minimize errors that might occur during signal processing phase. This setup is assisted with a light detection and localization system (LiDAL) that can passively obtain spatio-temporal indoor information of user presence and location for dynamic-user grouping. The designed LiDAL system helps to improve the estimation of channel state information (CSI) in realistic indoor network scenarios, where the CSI of indoor users might be noisy and/or highly correlated. We evaluate the performance of NOMA combined with RLNC by analyzing the probability of successful decoding compared to conventional NOMA and orthogonal schemes. In addition, we derive the Cramer-Rao Lower Bound (CRLB) to evaluate the accuracy of location estimation. The results show that the proposed RLNC-NOMA improves the probability of successful decoding and the overall system performance. The results also show the high accuracy of the unbiased location estimator and its assistant in reducing the imperfection of CSI, leading to high overall system performance.