Vehicle-to-Vehicle (V2V) communications are being proposed, tested and deployed to improve road safety and traffic efficiency. However, the automotive industry poses strict requirements for safety-critical applications, that call for reliable, low latency and high data rate communications. In this context, it is widely agreed that both Radio-Frequency (RF) technologies at mmWaves and Free-Space Optics (FSO) represent promising solutions, although their performances are severely degraded by transmitter-receiver misalignment due to the challenging high-mobility conditions. By combining RF and FSO technologies, this paper proposes a FSO-based V2V communication system where the pointing coordinates of laser sources are based on vehicle's information exchanged over a reliable low-rate RF link. Numerical simulations demonstrate that such compensation mechanism is mandatory to counteract the unavoidable misalignments induced by vehicle dynamics, and thus to enable FSO technology for V2V communications even in high mobility scenarios.