The focus of this work is on the design of Raptor codes for continuous variable Quantum key distribution (CV-QKD) systems. We design a highly efficient Raptor code for very low signal to noise ratios (SNRs), which enables CV-QKD systems to operate over long distances with a significantly higher secret key rate compared to conventional fixed rate codes. The degree distribution design of Raptor codes in the low SNR regime is formulated as a linear program, where a set of optimized degree distributions are also obtained through linear programming. Simulation results show that the designed code achieves efficiencies higher than 94\% for SNRs as low as -20 dB and -30 dB. We further propose a new error reconciliation protocol for CV-QKD systems by using Raptor codes and show that it can achieve higher secret key rates over long distances compared to existing protocols.