Consider the transmission of a polar code of block length $N$ and rate $R$ over a binary memoryless symmetric channel $W$ and let $P_e$ be the block error probability under successive cancellation decoding. In this paper, we develop new bounds that characterize the relationship of the parameters $R$, $N$, $P_e$, and the quality of the channel $W$ quantified by its capacity $I(W)$ and its Bhattacharyya parameter $Z(W)$. In previous work, two main regimes were studied. In the error exponent regime, the channel $W$ and the rate $R<I(W)$ are fixed, and it was proved that the error probability $P_e$ scales roughly as $2^{-\sqrt{N}}$. In the scaling exponent approach, the channel $W$ and the error probability $P_e$ are fixed and it was proved that the gap to capacity $I(W)-R$ scales as $N^{-1/μ}$. Here, $μ$ is called scaling exponent and this scaling exponent depends on the channel $W$. A heuristic computation for the binary erasure channel (BEC) gives $μ=3.627$ and it was shown that, for any channel $W$, $3.579 \le μ\le 5.702$. Our contributions are as follows. First, we provide the tighter upper bound $μ\le 4.714$ valid for any $W$. With the same technique, we obtain $μ\le 3.639$ for the case of the BEC, which approaches very closely its heuristically derived value. Second, we develop a trade-off between the gap to capacity $I(W)-R$ and the error probability $P_e$ as functions of the block length $N$. In other words, we consider a moderate deviations regime in which we study how fast both quantities, as functions of the block length $N$, simultaneously go to $0$. Third, we prove that polar codes are not affected by error floors. To do so, we fix a polar code of block length $N$ and rate $R$. Then, we vary the channel $W$ and we show that the error probability $P_e$ scales as the Bhattacharyya parameter $Z(W)$ raised to a power that scales roughly like $\sqrt{N}$.