Electromagnetic information theory (EIT) is one of the emerging topics for 6G communication due to its potential to reveal the performance limit of wireless communication systems. For EIT, the research foundation is reasonable and accurate channel modeling. Existing channel modeling works for EIT in non-line-of-sight (NLoS) scenario focus on far-field modeling, which can not accurately capture the characteristics of the channel in near-field. In this paper, we propose the near-field channel model for EIT based on electromagnetic scattering theory. We model the channel by using non-stationary Gaussian random fields and derive the analytical expression of the correlation function of the fields. Furthermore, we analyze the characteristics of the proposed channel model, e.g., channel degrees of freedom (DoF). Finally, we design a channel estimation scheme for near-field scenario by integrating the electromagnetic prior information of the proposed model. Numerical analysis verifies the correctness of the proposed scheme and shows that it can outperform existing schemes like least square (LS) and orthogonal matching pursuit (OMP).