In this work, we determine the generator polynomials for the Hermitian hulls and Hermitian sums of cyclic codes defined over the composite ring $\mathbb{F}_2 \times (\mathbb{F}_2 + v\mathbb{F}_2)$, where $v^2 = v$. Based on these structures, we develop quantum error-correcting (QEC) codes by applying the Hermitian dual version of Quantum Construction~X to the obtained Hermitian hulls and sums. Moreover, by employing matrix product code methods on linear complementary dual (LCD) codes defined over the same ring, we derive families of entanglement-assisted quantum error-correcting (EAQEC) codes.