This work investigates the energy-efficient resource allocation for layered-division multiplexing (LDM) based non-orthogonal multicast and unicast transmission in cell-free massive multiple-input multiple-output (MIMO) systems, where each user equipment (UE) performs wireless information and power transfer simultaneously. To begin with, the achievable data rates for multicast and unicast services are derived in closed form, as well as the received radio frequency (RF) power at each UE. Based on the analytical results, a nonsmooth and nonconvex optimization problem for energy efficiency (EE) maximization is formulated, which is however a challenging fractional programming problem with complex constraints. To suit the massive access setting, a first-order algorithm is developed to find both initial feasible point and the nearly optimal solution. Moreover, an accelerated algorithm is designed to improve the convergence speed. Numerical results demonstrate that the proposed first-order algorithms can achieve almost the same EE as that of second-order approaches yet with much lower computational complexity, which provides insight into the superiority of the proposed algorithms for massive access in cell-free massive MIMO systems.