The footprints of residential segregation have long been documented, yet the role of urban form as both medium and manifestation of segregation remains under-specified. We investigate whether the configuration of the built fabric may encode residential segregation in its spatial structure, hypothesising that built-form entropy (BFE) regimes are associated with the spatial distribution of income groups and their local clustering in non-linear ways. We examine this by quantifying BFE through a Shannon-based measure computed from building footprints, characterising income-based distributions using the Gini index and Moran's I, and placing both on a common spatial footing through a regular tessellation. Applying this framework to Sao Paulo, Latin America's largest city, we find non-linear relationships between BFE, income, and segregation: income levels and residential clustering increase toward both extremes of the entropy spectrum, with a stronger rise at the high-entropy end. This asymmetry suggests that high-entropy urban forms are associated with distinct spatial processes of segregation, including elite enclaving and incremental development in lower-income settlements, while low-entropy forms reflect more selective occupation shaped by planning and market filtering. Overall, the findings suggest that built form is more than a neutral backdrop, functioning as both affordance and signal of segregation.