The success of large language models (LLMs) depends heavily on large-scale, high-quality instruction-following and reinforcement datasets. However, generating such data through human annotation is prohibitively time-consuming particularly for domain-specific tasks like telecom network troubleshooting, where accurate responses require deep technical expertise and contextual understanding. In this paper, we present a fully automated, retrieval-augmented pipeline for generating synthetic question-answer (QA) pairs grounded in structured domain knowledge. Our multi-stage framework integrates a retriever, base generator, and refinement model to synthesize and enhance QA pairs using documents retrieved from a domain-specific knowledge graph. To ensure data quality, we employ customized RAGAS-based scoring to filter low-quality samples, producing a high-quality dataset suitable for reinforcement fine-tuning (RFT). We demonstrate our approach in a real-world telecom scenario focused on radio access network (RAN) troubleshooting. The resulting pipeline generates complex, context-rich troubleshooting solution plans without human intervention. This work offers a scalable solution for building instruction and reinforcement datasets in specialized domains, significantly reducing dependence on manual labeling while maintaining high technical fidelity.