A non-zero $\mathbb{F}$-linear map from a finite-dimensional commutative $\mathbb{F}$-algebra to $\mathbb{F}$ is called an $\mathbb{F}$-valued trace if its kernel does not contain any non-zero ideals. In this article, we utilize an $\mathbb{F}_2$-valued trace of the $\mathbb{F}_2$-algebra $\mathcal{R}_2:=\mathbb{F}_2[x]/\langle x^3-x\rangle$ to study binary subfield code $\mathcal{C}_D^{(2)}$ of $\mathcal{C}_D:=\{\left(x\cdot d\right)_{d\in D}: x\in \mathcal{R}_2^m\}$ for each defining set $D$ derived from a certain simplicial complex. For $m\in \mathbb{N}$ and $X\subseteq \{1, 2, \dots, m\}$, define $Δ_X:=\{v\in \mathbb{F}_2^m: \Supp(v)\subseteq X\}$ and $D:=(1+u^2)D_1+u^2D_2+(u+u^2)D_3,$ a subset of $\mathcal{R}_2^m,$ where $u=x+\langle x^3-x\rangle, D_1\in \{Δ_L, Δ_L^c\},\, D_2\in \{Δ_M, Δ_M^c\}$ and $ D_3\in \{Δ_N, Δ_N^c\}$, for $L, M, N\subseteq \{1, 2, \dots, m\}.$ The parameters and the Hamming weight distribution of the binary subfield code $\mathcal{C}_D^{(2)}$ of $\mathcal{C}_D$ are determined for each $D.$ These binary subfield codes are minimal under certain mild conditions on the cardinalities of $L, M$ and $N$. Moreover, most of these codes are distance-optimal. Consequently, we obtain a few infinite families of minimal, self-orthogonal and distance-optimal binary linear codes that are either $2$-weight or $4$-weight. It is worth mentioning that we have obtained several new distance-optimal binary linear codes.