This paper mainly describes our winning solution (team name: www) to Amazon ESCI Challenge of KDD CUP 2022, which achieves a NDCG score of 0.9043 and wins the first place on task 1: the query-product ranking track. In this competition, participants are provided with a real-world large-scale multilingual shopping queries data set and it contains query-product pairs in English, Japanese and Spanish. Three different tasks are proposed in this competition, including ranking the results list as task 1, classifying the query/product pairs into Exact, Substitute, Complement, or Irrelevant (ESCI) categories as task 2 and identifying substitute products for a given query as task 3. We mainly focus on task 1 and propose a semantic alignment system for multilingual query-product retrieval. Pre-trained multilingual language models (LM) are adopted to get the semantic representation of queries and products. Our models are all trained with cross-entropy loss to classify the query-product pairs into ESCI 4 categories at first, and then we use weighted sum with the 4-class probabilities to get the score for ranking. To further boost the model, we also do elaborative data preprocessing, data augmentation by translation, specially handling English texts with English LMs, adversarial training with AWP and FGM, self distillation, pseudo labeling, label smoothing and ensemble. Finally, Our solution outperforms others both on public and private leaderboard.