Beyond the success of Contrastive Language-Image Pre-training (CLIP), recent trends mark a shift toward exploring the applicability of lightweight vision-language models for resource-constrained scenarios. These models often deliver suboptimal performance when relying solely on a single image-text contrastive learning objective, spotlighting the need for more effective training mechanisms that guarantee robust cross-modal feature alignment. In this work, we propose CLIP-PING: Contrastive Language-Image Pre-training with Proximus Intrinsic Neighbors Guidance, a novel yet simple and efficient training paradigm designed to boost the performance of lightweight vision-language models with minimal computational overhead and lower data demands. CLIP-PING bootstraps unimodal features extracted from arbitrary pre-trained encoders to obtain intrinsic guidance of proximus neighbor samples, i.e., nearest-neighbor (NN) and cross nearest-neighbor (XNN). We find that extra contrastive supervision from these neighbors substantially boosts cross-modal alignment, enabling lightweight models to learn more generic features with rich semantic diversity. Extensive experiments reveal that CLIP-PING notably surpasses its peers in zero-shot generalization and cross-modal retrieval tasks. Specifically, a 5.5% gain on zero-shot ImageNet1K classification with 10.7% (I2T) and 5.7% (T2I) on Flickr30K retrieval, compared to the original CLIP when using ViT-XS image encoder trained on 3 million (image, text) pairs. Moreover, CLIP-PING showcases a strong transferability under the linear evaluation protocol across several downstream tasks.