5G new radio (NR) provides new opportunities for accurate positioning from a single reference station: large bandwidth combined with multiple antennas, at both the base station and user sides, allows for unparalleled angle and delay resolution. Nevertheless, positioning quality is affected by multipath and clock biases. We study, in terms of performance bounds and algorithms, the ability to localize a vehicle in the presence of multipath and unknown user clock bias. We find that when a sufficient number of paths is present, a vehicle can still be localized thanks to redundancy in the geometric constraints. Moreover, the 5G NR signals enable a vehicle to build up a map of the environment.