Energy supply on high mountains remains an open issue since grid connection is unavailable. In the past, diesel generators with lead-acid battery energy storage systems (ESSs) are applied in most cases. Recently, photovoltaic (PV) system with lithium-ion (Li-ion) battery ESS is an appropriate method for solving this problem in a greener way. In 2016, an off-grid PV system with Li-ion battery ESS has been installed in Paiyun Lodge on Mt. Jade (the highest lodge in Taiwan). After operation for more than 7 years, the aging problem of the whole electric power system becomes a critical issue for long-term usage. In this work, a method is established for analyzing the massive energy data (over 7 million rows) and estimating the health of the Li-ion battery system, such as daily operation patterns as well as C-rate, temperature, and accumulated energy distributions. The accomplished electric power improvement project dealing with the power system aging is reported. Based on the long-term usage experience, a simple cost analysis model between lead-acid and Li-ion battery systems is built, explaining that the expensive Li-ion batteries can compete with the cheap lead-acid batteries for long-term usage on high mountains. This case study provides engineers and researchers a fundamental understanding of the long-term usage of off-grid PV ESSs and engineering on high mountains.