This letter proposes a block sparse Bayesian learning (BSBL) algorithm of non-circular (NC) signals for direction-of-arrival (DOA) estimation, which is suitable for arbitrary unknown NC phases. The block sparse NC signal representation model is constructed through a permutation strategy, capturing the available intra-block structure information to enhance recovery performance. After that, we create the sparse probability model and derive the cost function under BSBL framework. Finally, the fast marginal likelihood maximum (FMLM) algorithm is introduced, enabling the rapid implementation of signal recovery by the addition and removal of basis functions. Simulation results demonstrate the effectiveness and the superior performance of our proposed method.