Free-space optical time transfer that features high precision and flexibility will act a crucial role in near-future ground-to-satellite/inter-satellite clock networks and outdoor timing services. Here we propose a free-space optical flexible-binary-offset-carrier-modulated (FlexBOC-modulated) time transfer method. The utilized FlexBOC modulation could yield a comparative precision, although its occupied bandwidth is tremendously reduced by at least 97.5% compared to optical binary phase modulation. Meanwhile, the adoption of optical techniques eliminates the multi-path effect that is major limit in the current microwave satellite time transfer system. What's more, the time interval measurement avoids a continuous link that may be routinely broken by physical obstructions. For verification, a time transfer experiment with our home-built system between two sites separated by a 30-m free-space path outside the laboratory was conducted. Over a 15 h period, the time deviation is 2.3 ps in a 1-s averaging time, and averages down to 1.0 ps until ~60 s. The fractional frequency instability exhibits 4.0E-12 at a gate time of 1 s, and approaches to 2.6E10-15 at 10000 s.