The inspection of power transmission line has achieved notable achievements in the past few years, primarily due to the integration of deep learning technology. However, current inspection approaches continue to encounter difficulties in generalization and intelligence, which restricts their further applicability. In this paper, we introduce Power-LLaVA, the first large language and vision assistant designed to offer professional and reliable inspection services for power transmission line by engaging in dialogues with humans. Moreover, we also construct a large-scale and high-quality dataset specialized for the inspection task. By employing a two-stage training strategy on the constructed dataset, Power-LLaVA demonstrates exceptional performance at a comparatively low training cost. Extensive experiments further prove the great capabilities of Power-LLaVA within the realm of power transmission line inspection. Code shall be released.