Second-generation Starlink Direct-to-Cell (DTC) satellites carry an additional payload for direct cellular phone connectivity whose unintended electromagnetic radiation (UEMR) at sub-300 MHz frequencies has not been individually characterised. We reanalyse 112,534 detections from 1,806 Starlink satellites observed with the Engineering Development Array version 2 (EDA2) at 21 frequencies between 72.685 and 234.375 MHz (Grigg et al. 2025), separating 175 DTC and 1,623 Ku-only v2-Mini comparison satellites via the McDowell General Catalogue (McDowell 2020). DTC satellites emit a range-corrected flux density 1.45x that of the Ku-only comparison (Cliff's delta = +0.30, p = 2.6e-11). At 230.469 MHz the XX detection fraction reaches 0.811 against a 0.481 baseline (p ~ 1e-274), and 11 of 21 frequency channels show Benjamini-Hochberg-significant polarisation anomalies. The DTC population is brighter in eclipse than in sunlight (illuminated/eclipsed flux density ratio 0.47) while the Ku-only comparison shows the opposite sense (1.18); the reversal persists across altitude, sub-satellite latitude, frequency, and launch-epoch matching. The reversal strongly disfavours UEMR mechanisms that scale monotonically with instantaneous solar photocurrent and favours an active on-board source whose effective duty cycle is larger at lower equilibrium temperature. Within the 230.469 MHz coarse channel, fine-channel inspection isolates the excess to a single ~24 kHz bin near 230.627 MHz, tail-driven and absent at five control channels. Three falsifiable mechanism-discrimination tests show this feature is not coincident with the LOFAR-resolved Bassa et al. (2024) clock fundamentals, is unresolved at the EDA2 24 kHz resolution, and is heterogeneously expressed across the v2-Mini fleet rather than driven by a few permanently bright units or by uniform thermal scaling.