Multi-sensor Simultaneous Localization and Mapping (SLAM) is essential for Unmanned Aerial Vehicles (UAVs) performing agricultural tasks such as spraying, surveying, and inspection. However, real-world, multi-modal agricultural UAV datasets that enable research on robust operation remain scarce. To address this gap, we present AgriLiRa4D, a multi-modal UAV dataset designed for challenging outdoor agricultural environments. AgriLiRa4D spans three representative farmland types-flat, hilly, and terraced-and includes both boundary and coverage operation modes, resulting in six flight sequence groups. The dataset provides high-accuracy ground-truth trajectories from a Fiber Optic Inertial Navigation System with Real-Time Kinematic capability (FINS_RTK), along with synchronized measurements from a 3D LiDAR, a 4D Radar, and an Inertial Measurement Unit (IMU), accompanied by complete intrinsic and extrinsic calibrations. Leveraging its comprehensive sensor suite and diverse real-world scenarios, AgriLiRa4D supports diverse SLAM and localization studies and enables rigorous robustness evaluation against low-texture crops, repetitive patterns, dynamic vegetation, and other challenges of real agricultural environments. To further demonstrate its utility, we benchmark four state-of-the-art multi-sensor SLAM algorithms across different sensor combinations, highlighting the difficulty of the proposed sequences and the necessity of multi-modal approaches for reliable UAV localization. By filling a critical gap in agricultural SLAM datasets, AgriLiRa4D provides a valuable benchmark for the research community and contributes to advancing autonomous navigation technologies for agricultural UAVs. The dataset can be downloaded from: https://zhan994.github.io/AgriLiRa4D.