As the underlying foundation of a digital twin network (DTN), a digital twin channel (DTC) can accurately depict the process of radio propagation in the air interface to support the DTN-based 6G wireless network. Since radio propagation is affected by the environment, constructing the relationship between the environment and radio wave propagation is the key to improving the accuracy of DTC, and the construction method based on artificial intelligence (AI) is the most concentrated. However, in the existing methods, the environment information input into the neural network (NN) has many dimensions, and the correlation between the environment and the channel relationship is unclear, resulting in a highly complex relationship construction process. To solve this issue, in this paper, we propose a construction method of radio environment knowledge (REK) inspired by the electromagnetic wave property to quantify the contribution of radio propagation. Specifically, a range selection scheme for effective environment information based on random geometry is proposed to reduce the redundancy of environment information. We quantify the contribution of radio propagation reflection, diffraction and scatterer blockage using environment information and propose a flow chart of REK construction to replace the feature extraction process partially based on NN. To validate REK's effectiveness, we conduct a path loss prediction task based on a lightweight convolutional neural network (CNN) employing a simple two-layer convolutional structure. The results show that the accuracy of the range selection method reaches 90\%; the constructed REK maintains the prediction error of 0.3 and only needs 0.04 seconds of testing time, effectively reducing the network complexity.