This article describes an efficient training method for online streaming attention-based encoder-decoder (AED) automatic speech recognition (ASR) systems. AED models have achieved competitive performance in offline scenarios by jointly optimizing all components. They have recently been extended to an online streaming framework via models such as monotonic chunkwise attention (MoChA). However, the elaborate attention calculation process is not robust for long-form speech utterances. Moreover, the sequence-level training objective and time-restricted streaming encoder cause a nonnegligible delay in token emission during inference. To address these problems, we propose CTC synchronous training (CTC-ST), in which CTC alignments are leveraged as a reference for token boundaries to enable a MoChA model to learn optimal monotonic input-output alignments. We formulate a purely end-to-end training objective to synchronize the boundaries of MoChA to those of CTC. The CTC model shares an encoder with the MoChA model to enhance the encoder representation. Moreover, the proposed method provides alignment information learned in the CTC branch to the attention-based decoder. Therefore, CTC-ST can be regarded as self-distillation of alignment knowledge from CTC to MoChA. Experimental evaluations on a variety of benchmark datasets show that the proposed method significantly reduces recognition errors and emission latency simultaneously. The robustness to long-form and noisy speech is also demonstrated. We compare CTC-ST with several methods that distill alignment knowledge from a hybrid ASR system and show that the CTC-ST can achieve a comparable tradeoff of accuracy and latency without relying on external alignment information. The best MoChA system shows recognition accuracy comparable to that of RNN-transducer (RNN-T) while achieving lower emission latency.