CTC-based streaming ASR has gained significant attention in real-world applications but faces two main challenges: accuracy degradation in small chunks and token emission latency. To mitigate these challenges, we propose Delayed-KD, which applies delayed knowledge distillation on CTC posterior probabilities from a non-streaming to a streaming model. Specifically, with a tiny chunk size, we introduce a Temporal Alignment Buffer (TAB) that defines a relative delay range compared to the non-streaming teacher model to align CTC outputs and mitigate non-blank token mismatches. Additionally, TAB enables fine-grained control over token emission delay. Experiments on 178-hour AISHELL-1 and 10,000-hour WenetSpeech Mandarin datasets show consistent superiority of Delayed-KD. Impressively, Delayed-KD at 40 ms latency achieves a lower character error rate (CER) of 5.42% on AISHELL-1, comparable to the competitive U2++ model running at 320 ms latency.