The underlying dependence structure between two random variables can be described in manifold ways. This includes the examination of certain dependence properties such as lower tail decreasingness (LTD), stochastic increasingness (SI) or total positivity of order 2, the latter usually considered for a copula (TP2) or (if existent) its density (d-TP2). In the present paper we investigate total positivity of order 2 for a copula's Markov kernel (MK-TP2 for short), a positive dependence property that is stronger than TP2 and SI, weaker than d-TP2 but, unlike d-TP2, is not restricted to absolutely continuous copulas, making it presumably the strongest dependence property defined for any copula (including those with a singular part such as Marshall-Olkin copulas). We examine the MK-TP2 property for different copula families, among them the class of Archimedean copulas and the class of extreme value copulas. In particular we show that, within the class of Archimedean copulas, the dependence properties SI and MK-TP2 are equivalent.