This paper deduces exponential matrix concentration from a Poincaré inequality via a short, conceptual argument. Among other examples, this theory applies to matrix-valued functions of a uniformly log-concave random vector. The proof relies on the subadditivity of Poincaré inequalities and a chain rule inequality for the trace of the matrix Dirichlet form. It also uses a symmetrization technique to avoid difficulties associated with a direct extension of the classic scalar argument.