Consider a non-autonomous continuous-time linear system in which the time-dependent matrix determining the dynamics is piecewise constant and takes finitely many values $A_1, \dotsc, A_N$. This paper studies the equality cases between the maximal Lyapunov exponent associated with the set of matrices $\{A_1, \dotsc, A_N\}$, on the one hand, and the corresponding ones for piecewise deterministic Markov processes with modes $A_1, \dotsc, A_N$, on the other hand. A fundamental step in this study consists in establishing a result of independent interest, namely, that any sequence of Markov processes associated with the matrices $A_1,\dotsc, A_N$ converges, up to extracting a subsequence, to a Markov process associated with a suitable convex combination of those matrices.