This paper is to investigate the spectral properties of sample covariance matrices under a more general population. We consider a class of matrices of the form $\mathbf S_n=\frac1n\mathbf B_n\mathbf X_n\mathbf X_n^*\mathbf B_n^*$, where $\mathbf B_n$ is a $p\times m$ non-random matrix and $\mathbf X_n$ is an $m\times n$ matrix consisting of i.i.d standard complex entries. $p/n\to c\in (0,\infty)$ as $n\to \infty$ while $m$ can be arbitrary. We proved that under some mild assumptions, with probability 1, there will be no eigenvalues in any closed interval contained in an open interval outside the supports of the limiting distribution $F_{c_n,H_n}$, for all sufficiently large $n$. An extension of Bai-Yin law is also obtained.