A pathwise large deviation result is proved for the pure jump models of $k$-nary interacting particle system introduced by Kolokoltsov that generalize classical Boltzmann's collision model, Smoluchovski's coagulation model and many others. The upper bound is obtained by following the standard methods of using a process "perturbed" by a regular function. To show the lower bound, we propose a family of orthogonal martingale measures and prove a coupling for the general perturbations. The rate function is studied based on the idea of Léonard with a simplification by considering the conjugation of integral functionals on a subspace of $L^{\infty}$. General "gelling" solutions in the domain of the rate function are also discussed.