For any Borel probability measure on $\mathbb{R}^n$, we may define a family of eccentricity tensors. This new notion, together with a tensorization trick, allows us to prove an energy minimization property for rotationally invariant probability measures. We use this theory to give a new proof of the Welch bounds, and to improve upon them for collections of real vectors. In addition, we are able to give elementary proofs for two theorems characterizing probability measures optimizing one-parameter families of energy integrals on the sphere. We are also able to explain why a phase transition occurs for optimizers of these two families.