A $d$-dimensional simplex in Euclidean space is called orthocentric if all of its altitudes intersect at a single point, referred to as the orthocenter. We explicitly compute the internal and external angles at all faces of an orthocentric simplex. To this end, we introduce a parametric family of polyhedral cones, called orthocentric cones, and derive formulas for their angles and, more generally, for their conic intrinsic volumes. We characterize the tangent and normal cones of orthocentric simplices in terms of orthocentric cones with explicit parameters. Depending on whether the orthocenter lies inside the simplex, on its boundary, or outside, the simplex is classified as acute, rectangular, or obtuse, respectively. The solid angle formulas differ in these three cases. As a probabilistic application of the angle formulas, we explicitly compute the expected number of $k$-dimensional faces and the expected volume of the random polytope $[g_1/τ_1, \ldots, g_n/τ_n]$, where $g_1, \ldots, g_n$ are independent standard Gaussian vectors in $\mathbb{R}^d$, and $τ_1, \ldots, τ_n > 0$ are constants.