We consider the stationary measure of the asymmetric simple exclusion process (ASEP) on a finite interval in $\mathbb{Z}$ with open boundaries. Fixing all the jump rates and letting the system size approach infinity, the height profile of such a sequence of stationary measures satisfies a large deviation principle (LDP), whose rate function was predicted in the physics work arXiv:cond-mat/0205353. In this paper, we provide the first rigorous proof of the large deviation principle in the "fan region" part of the phase diagram. Our proof relies on two key ingredients: a two-layer expression of the stationary measure of open ASEP, arising from the Enaud-Derrida representation arXiv:cond-mat/0307023 of the matrix product ansatz, and the large deviation principle of the open totally asymmetric simple exclusion process (TASEP) recently established in arXiv:2403.03275.