We consider singular control in inventory management under Knightian uncertainty, where decision makers have a smooth ambiguity preference over Gaussian-generated priors. We demonstrate that continuous-time smooth ambiguity is the infinitesimal limit of Kalman-Bucy filtering with recursive robust utility. Additionally, we prove that the cost function can be determined by solving forward-backward stochastic differential equations with quadratic growth. With a sufficient condition and utilising variational inequalities in a viscosity sense, we derive the value function and optimal control policy. By the change-of-coordinate technique, we transform the problem into two-dimensional singular control, offering insights into model learning and aligning with classical singular control free boundary problems. We numerically implement our theory using a Markov chain approximation, where inventory is modeled as cash management following an arithmetic Brownian motion. Our numerical results indicate that the continuation region can be divided into three key areas: (i) the target region; (ii) the region where it is optimal to learn and do nothing; and (iii) the region where control becomes predominant and learning should inactive. We demonstrate that ambiguity drives the decision maker to act earlier, leading to a smaller continuation region. This effect becomes more pronounced at the target region as the decision maker gains confidence from a longer learning period. However, these dynamics do not extend to the third region, where learning is excluded.