This article studies the Gram random matrix model $G=\frac1TΣ^{\rm T}Σ$, $Σ=σ(WX)$, classically found in the analysis of random feature maps and random neural networks, where $X=[x_1,\ldots,x_T]\in{\mathbb R}^{p\times T}$ is a (data) matrix of bounded norm, $W\in{\mathbb R}^{n\times p}$ is a matrix of independent zero-mean unit variance entries, and $σ:{\mathbb R}\to{\mathbb R}$ is a Lipschitz continuous (activation) function --- $σ(WX)$ being understood entry-wise. By means of a key concentration of measure lemma arising from non-asymptotic random matrix arguments, we prove that, as $n,p,T$ grow large at the same rate, the resolvent $Q=(G+γI_T)^{-1}$, for $γ>0$, has a similar behavior as that met in sample covariance matrix models, involving notably the moment $Φ=\frac{T}n{\mathbb E}[G]$, which provides in passing a deterministic equivalent for the empirical spectral measure of $G$. Application-wise, this result enables the estimation of the asymptotic performance of single-layer random neural networks. This in turn provides practical insights into the underlying mechanisms into play in random neural networks, entailing several unexpected consequences, as well as a fast practical means to tune the network hyperparameters.