We study large deviations for random walks on Lie groups defined by $σ_n^n = \exp(\frac1nX_1)\cdots\exp(\frac1nX_n)$, where $\{X_n\}_{n\geq1}$ is an i.i.d sequence of bounded random variables in the Lie algebra $\mathfrak{g}$. We follow a similar approach as in the proof of large deviations for geodesic random walks as given in [Ver19]. This approach makes it possible to simply rescale the increments of the random walk, without having to resort to dilations in order to reduce the influence of higher order commutators. Finally, we will apply this large deviation result to the Lie group of stochastic matrices.