In the mating-of-trees approach to Schramm-Loewner evolution (SLE) and Liouville quantum gravity (LQG), it is natural to consider two pairs of correlated Brownian motions coupled together. This arises in the scaling limit of bipolar-orientation-decorated planar maps (Gwynne-Holden-Sun, 2016) and in the related skew Brownian permuton studied by Borga et al. There are two parameters that can be used to index the coupling between the two pairs of Brownian motions, denoted as $p$ and $θ$ in the literature: $p$ describes the Brownian motions, whereas $θ$ describes the SLE curves on LQG surfaces. In this paper, we derive an exact relation between the two parameters and demonstrate its application to computing statistics of the skew Brownian permuton. Our derivation relies on the synergy between mating-of-trees and Liouville conformal field theory (LCFT), where the boundary three-point function in LCFT provide the exact solvable inputs.