We propose a refined but natural notion of toric degenerations that respect a given embedding and show that within this framework a Gorenstein Fano variety can only be degenerated to a Gorenstein Fano toric variety if it is embedded via its anticanonical embedding. This also gives a precise criterion for reflexive polytopes to appear, which might be required for applications in mirror symmetry. For the proof of this statement we will study polytopes whose polar dual is a lattice polytope. As a byproduct we generalize a connection between the number of lattice points in a rational convex polytope and the Euler characteristic of an associated torus invariant rational Weil divisor, allowing us to show that Ehrhart-Macdonald Reciprocity and Serre Duality are equivalent statements for a broad class of varieties. Additionally, we conjecture a necessary and sufficient condition for the Ehrhart quasi-polynomial of a rational convex polytope to be a polynomial. Finally, we show that the anticanonical line bundle on a Gorenstein Fano variety with at worst rational singularities is uniquely determined by a combinatorial condition of its Hilbert polynomial.