We investigate the combinatorial structure of unrefinable partitions through their correspondence with numerical sets and Young diagrams. Building on the bijection introduced by Keith and Nath, we apply a general geometric criterion that links the unrefinability of a partition directly to the hook lengths of its associated Young diagram. This criterion provides a structural method for the characterization of any unrefinable partition. Using this general framework, we revisit the correspondence results between maximal unrefinable partitions and partitions into distinct parts, previously established using enumerative methods. We provide alternative and purely combinatorial proofs of these bijections, focusing on the rigid symmetry structures of the Young diagrams. In the triangular weight case, we show that the corresponding diagrams are quasi-symmetric, i.e. symmetric up to a single extra column. We extend this analysis to the nontriangular case, showing that the diagrams either exhibit this same quasi-symmetric structure or are perfectly self-conjugate, depending on the maximal part.