Let $\varphi_{n,K}$ denote the largest angle in all the triangles with vertices among the $n$ points selected at random in a compact convex subset $K$ of $\mathbb{R}^d$ with nonempty interior, where $d\ge2$. It is shown that the distribution of the random variable $λ_d(K)\,\frac{n^3}{3!}\,(π-\varphi_{n,K})^{d-1}$, where $λ_d(K)$ is a certain positive real number which depends only on the dimension $d$ and the shape of $K$, converges to the standard exponential distribution as $n\to\infty$. By using the Steiner symmetrization, it is also shown that $λ_d(K)$ -- which is referred to in the paper as the elongation of $K$ -- attains its minimum if and only if $K$ is a ball $B^{(d)}$ in $\mathbb{R}^d$. Finally, the asymptotics of $λ_d(B^{(d)})$ for large $d$ is determined.