We construct an explicit family of 3XOR instances which is hard for $O(\sqrt{\log n})$ levels of the Sum-of-Squares hierarchy. In contrast to earlier constructions, which involve a random component, our systems can be constructed explicitly in deterministic polynomial time. Our construction is based on the high-dimensional expanders devised by Lubotzky, Samuels and Vishne, known as LSV complexes or Ramanujan complexes, and our analysis is based on two notions of expansion for these complexes: cosystolic expansion, and a local isoperimetric inequality due to Gromov. Our construction offers an interesting contrast to the recent work of Alev, Jeronimo and the last author~(FOCS 2019). They showed that 3XOR instances in which the variables correspond to vertices in a high-dimensional expander are easy to solve. In contrast, in our instances the variables correspond to the edges of the complex.