A permutation $σ=σ_1 σ_2 \cdots σ_n$ has a descent at $i$ if $σ_i>σ_{i+1}$. A descent $i$ is called a peak if $i>1$ and $i-1$ is not a descent. The size of the set of all permutations of $n$ with a given descent set is a polynomials in $n$, called the polynomial. Similarly, the size of the set of all permutations of $n$ with a given peak set, adjusted by a power of $2$ gives a polynomial in $n$, called the peak polynomial. In this work we give a unitary expansion of descent polynomials in terms of peak polynomials. Then we use this expansion to give a combinatorial interpretation of the coefficients of the peak polynomial in a binomial basis, thus giving a new proof of the peak polynomial positivity conjecture.