In toric topology, to a simplicial complex $K$ with $m$ vertices, one associates two spaces, the moment-angle complex $\mathcal{Z}_K$ and the Davis-Januszkiewicz space $DJ_K$. These spaces are connected by a homotopy fibration $\mathcal{Z}_K\to DJ_K\to(\mathbb{C}P^\infty)^m$. In this paper, we show that the map $\mathcal{Z}_K\to DJ_K$ is identified with a wedge of iterated (higher) Whitehead products for a certain class of simplicial complexes $K$ including dual shellable complexes. We will prove the result in a more general setting of polyhedral products.