We first compute the denominator formulas for quantum affine algebras of all exceptional types. Then we prove the isomorphisms among Grothendieck rings of categories $C_Q^{(t)}$ $(t=1,2,3)$, $\mathscr{C}_{\mathscr{Q}}^{(1)}$ and $\mathscr{C}_{\mathfrak{Q}}^{(1)}$. These results give Dorey's rule for all exceptional affine types, prove the conjectures of Kashiwara-Kang-Kim and Kashiwara-Oh, and provides the partial answers of Frenkel-Hernandez on Langlands duality for finite dimensional representations of quantum affine algebras of exceptional types.