We introduce the class of MAT-free hyperplane arrangements which is based on the Multiple Addition Theorem by Abe, Barakat, Cuntz, Hoge, and Terao. We also investigate the closely related class of MAT2-free arrangements based on a recent generalization of the Multiple Addition Theorem by Abe and Terao. We give classifications of the irreducible complex reflection arrangements which are MAT-free respectively MAT2-free. Furthermore, we ask some questions concerning relations to other classes of free arrangements.