This paper is devoted to the study of eigenvalue region of the doubly stochastic matrices which are also permutative, that is, each row of such a matrix is a permutation of any other row. We call these matrices as permutative doubly stochastic (PDS) matrices. A method is proposed to obtain symbolic representation of all PDS matrices of order $n$ by finding equivalence classes of permutationally similar symbolic PDS matrices. This is a hard problem in general as it boils down to finding all Latin squares of order $n.$ However, explicit symbolic representation of matrices in these classes are determined in this paper when $n=2, 3, 4.$ It is shown that eigenvalue regions are same for doubly stochastic matrices and PDS matrices when $n=2, 3.$ It is also established that this is no longer true for $n=4,$ and two line segments are determined which belong to the eigenvalue region of doubly stochastic matrices but not in the eigenvalue region of PDS matrices. Thus a conjecture is developed for the boundary of the eigenvalue region of PDS matrices of order $4.$ Finally, inclusion theorems for eigenvalue region of PDS matrices are proved when $n\geq 2.$